JP EN

Membersメンバー

  1. TOP
  2. Members
  3. 林 裕樹

林 裕樹

Hiroki Hayashi

特任准教授
TEL
011-706-9654
FAX
011-706-9655
E-mail
hhayashi@icredd.hokudai.ac.jp
ROOM
創成科学研究棟05-116
  1. Trans-Selective Carboxylative Cyclization of 1,6-Dienes Using the CO2 Radical Anion

    Song, Y.; Hayashi, H.; Mangaonkar, S.; Mita, T. Chem. Lett. 2024, 53, in press.

    DOI : 10.1093/chemle/upae149

  2. Strain-Releasing Ring-Opening Diphosphinations for the Synthesis of Diphosphine Ligands with Cyclic Backbones

    Krishnan, C. G.; Takano, H.; Katsuyama, H.; Kanna, W.; Hayashi, H.; Mita, T. JACS Au 2024, 4, in press.

    DOI : 10.1021/jacsau.4c00347

  3. γ-Butyrolactone Synthesis from Allylic Alcohols Using the CO2 Radical Anion

    Mangaonkar, S. R.; Hayashi, H.; Kanna, W.; Debbarma, S.; Harabuchi, Y.; Maeda, S.; Mita, T. Precis. Chem. 2024, 2, 88 - 95.

    DOI : 10.1021/prechem.3c00117

  4. Revisiting the Electrochemical Carboxylation of Naphthalene with CO2: Selective Monocarboxylation of 2-Substituted Naphthalenes

    Rawat, V. K.; Hayashi, H.; Katsuyama, H.; Mangaonkar, S. R.; Mita, T. Org. Lett. 2023, 25, 4231 - 4235.

    DOI : 10.1021/acs.orglett.3c01033

  5. Quantum Chemical Calculations for Reaction Prediction in the Development of Synthetic Methodologies

    Hayashi, H.; Maeda, S.; Mita, T. Chem. Sci. 2023, 14, 11601 - 11616 .

    DOI : 10.1039/D3SC03319H

  6. Synthesis of Bicyclo[1.1.1]pentane (BCP)-Based Straight-Shaped Diphosphine Ligands

    Takano, H.; Katsuyama, H.; Hayashi, H.; Harukawa, M.; Tsurui, M.; Shoji, S.; Hasegawa, Y.; Maeda, S.; Mita, T. Angew. Chem., Int. Ed. 2023, 62, e202303435.

    DOI : 10.1002/anie.202303435

  7. Photoredox/HAT-Catalyzed Dearomative Nucleophilic Addition of the CO2 Radical Anion to (Hetero)Aromatics

    Mangaonkar, S. R.; Hayashi, H.; Takano, H.; Kanna, W.; Maeda, S.; Mita, T. ACS Catal. 2023, 13, 2482 - 2488.

    DOI : 10.1021/acscatal.2c06192

  8. Oxidation and Reduction Pathways in the Knowles Hydroamination via a Photoredox-Catalyzed Radical Reaction

    Harabuchi, Y.; Hayashi, H.; Takano, H.; Mita, T.; Maeda, S. Angew. Chem., Int. Ed. 2023, 62, e202211936.

    DOI : 10.1002/anie.202211936

  9. Toward ab initio Reaction Discovery Using the Artificial Force Induced Reaction Method

    Maeda, S.; Harabuchi, Y.; Hayashi, H.; Mita, T. Annu. Rev. Phys. Chem. 2023, 74, 287 - 311.

    DOI : 10.1146/annurev-physchem-102822-101025

  10. Prediction of High-Yielding Single-Step or Cascade Pericyclic Reactions for the Synthesis of Complex Synthetic Targets

    Mita, T.; Takano, H.; Hayashi, H.; Kanna, W.; Harabuchi, Y.; Houk, K. N.; Maeda, S. J. Am. Chem. Soc. 2022, 144, 22985 - 23000.

    DOI : 10.1021/jacs.2c09830

  11. A Theory-driven Synthesis of Symmetric and Unsymmetric 1,2-Bis(diphenylphosphino)ethane Analogues via Radical Difunctionalization of Ethylene

    Takano, H.; Katsuyama, H.; Hayashi, H.; Kanna, W.; Harabuchi, Y.; Maeda, S.; Mita, T. Nat. Commun. 2022, 13, 7034.

    DOI : 10.1038/s41467-022-34546-5

  12. In Silico Reaction Screening with Difluorocarbene for N-Difluoroalkylative Dearomatization of Pyridines

    Hayashi, H.; Katsuyama, H.; Takano, H.; Harabuchi, Y.; Maeda, S.; Mita, T. Nat. Synth. 2022, 1, 804 - 814.

    DOI : 10.1038/s44160-022-00128-y

  13. Iridium(III)-Catalyzed Asymmetric Site-Selective Carbene C–H Insertion during Late-Stage Transformation

    Yamakawa, Y.; Ikuta, T.; Hayashi, H.; Hashimoto, K.; Fujii, R.; Kawashima, K.; Mori, S.; Uchida, T.; Katsuki, T. J. Org. Chem. 2022, 87, 6769 - 6780.

    DOI : 10.1021/acs.joc.2c00470

  14. Electrochemical Dearomative Dicarboxylation of Heterocycles with Highly Negative Reduction Potentials

    You, Y.; Kanna, W.; Takano, H.; Hayashi, H.; Maeda, S.; Mita, T. J. Am. Chem. Soc. 2022, 144, 3685 - 3695.

    DOI : 10.1021/jacs.1c13032

  15. Radical Difunctionalization of Gaseous Ethylene Guided by Quantum Chemical Calculations: Selective Incorporation of Two Molecules of Ethylene

    Takano, H.; You, Y.; Hayashi, H.; Harabuchi, Y.; Maeda, S.; ACS OmegaMita, T. ACS Omega 2021, 6, 33846 - 33854.

    DOI : 10.1021/acsomega.1c05102

  16. Carboxylation of a Palladacycle Formed via C(sp3)-H Activation: Theory-Driven Reaction Design

    Kanna, W.; Harabuchi, Y.; Takano, H.; Hayashi, H.; Maeda, S.; Mita, T. Chem. Asian J. 2021, 16, 4072 - 4080.

    DOI : 10.1002/asia.202100989

  17. Synthesis of Difluoroglycine Derivatives from Amines, Difluorocarbene, and CO2: Computational Design, Scope, and Application

    Hayashi, H.; Takano, H.; Katsuyama, H.; Harabuchi, Y.; Maeda, S.; Mita, T. Chem. Eur. J. 2021, 27, 10040 - 10047.

    DOI : 10.1002/chem.202100812

  18. Ruthenium-Catalyzed Asymmetric N-Acyl Nitrene Transfer Reaction: Imidation of Sulfide

    Yoshitake, M; Hayashi, H.; Uchida, T. Org. Lett. 2020, 22, 4021 - 4025.

    DOI : 10.1021/acs.orglett.0c01373

  19. Non-Heme-Type Ruthenium Catalyzed Chemo- and Site-Selective C–H Oxidation

    Doiuchi, D.; Nakamura, T.; Hayashi, H.; Uchida, T. Chem. Asian J. 2021, 15, 762 - 765.

    DOI : 10.1002/asia.202000134

  20. Iron-Catalyzed Asymmetric Inter- and Intramolecular Aerobic Oxidative Dearomatizing Spirocyclization of 2-Naphthols

    Oguma, T.; Doiuchi, D.; Fujitomo, C.; Kim, C.; Hayashi, H.; Uchida, T.; Katsuki, T. Asian J. Org. Chem. 2020, 9, 404 - 404-415.

    DOI : 10.1002/ajoc.201900602

  21. Nitrene Transfer Reactions for Asymmetric C-H Amination: Recent Development

    Hayashi, H.; Uchida, T. Eur. J. Org. Chem. 2020, 8, 909 - 916.

    DOI : 10.1002/ejoc.201901562

  22. Ruthenium-Catalyzed Cross-Selective Asymmetric Oxidative Coupling of Arenols

    Hayashi, H.; Ueno, T.; Kim, C.; Uchida, T. Org. Lett. 2020, 22, 1469 - 1474.

    DOI : 10.1021/acs.orglett.0c00048

  23. Chemoselective, Enzymatic C–H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor

    Dydio, P.; Key, H. M.; Hayashi, H.; Clark, D. S.; Hartwig, J. F. J. Am. Chem. Soc. 2017, 139, 1750 - 1753.

    DOI : 10.1021/jacs.6b11410

  24. Chiral Ammonium Hypoiodite Salt-catalyzed Enantioselective Oxidative Cycloetherification to 2-Acyl Tetrahydrofurans

    Uyanik, M.; Hayashi, H.; Iwata, H.; Ishihara, K. Chem. Lett. 2015, 45, 353 - 355.

    DOI : 10.1246/cl.160004

  25. High-Turnover Hypoiodite Catalysis for Asymmetric Synthesis of Tocopherols

    Uyanik, M.; Hayashi, H.; Ishihara, K. Science 2014, 345, 291 - 294.

    DOI : 10.1126/science.1254976

Contactお問い合わせ

美多 剛 教授

Tsuyoshi Mita